Each year, crop producers are blitzed with a new concept or
product which,
if used, will solve all production problems. The latest promotion revolves
around
the claim that the ratio of calcium to magnesium in soils has a major
effect
on crop yield. Looking at this concept in detail, there are claims that
there is an
IDEAL ratio of calcium to magnesium that can be easily adjusted. Is this
concept
valid for Minnesota soils? Is this ratio really something that I should
be concerned
about? These are two of the many questions that crop producers are asking
as we head
into the 2003 planting season.
The ratio concept is not new. It evolved from research conducted with acid
sandy
soils in New Jersey using alfalfa as the test crop. In order to understand
the
concept, it's important to describe some facts of fundamental soil chemistry.
The best place to start is to introduce the concept of exchange sites. These
sites are negative electrical charges associated with the clay size particles
and
soil organic matter. Cations are
plant nutrients with a positive electrical charge calcium (Ca++),
magnesium (Mg++), and potassium (K+) are three cations
found in a
wide range of concentrations in all soils.

FIGURE
2.
These cations are found in a thin film of water that exists around plant root
hairs and
the clay particles. These positively charged plant nutrients are attracted
to the
negative electrical charge of the clay minerals and soil organic matter. This
attraction is illustrated in Figure 2.
Those that promote the ratio concept believe that the ratio of calcium to magnesium
associated with the exchange sites should be about 6.5 to 1.0. They further
believe
that optimum yields cannot be produced unless this ratio is 6.5 to 1.0.
Since the introduction of this concept, various research projects have been designed
to
evaluate the effect of this ratio on crop production (yield). Some of the
results of
those research efforts are summarized in the tables that follow.
In research in Wisconsin, the Ca:Mg ratio was changed by adding either sources
of calcium
or magnesium to the soil. A wide range in ratios was produced (Table 1). Alfalfa
was the test crop. The ratio had no effect on alfalfa production. Neither
the low nor the high ratios had any effect on alfalfa yield.
Table 1. Effect of various Ca:Mg ratios in two contrasting soils
on alfalfa
yield.
| Ca:Mg Ratio |
Yield |
| |
ton/acre |
| Theresa silt loam: |
|
| 2.28 |
3.31 |
| 3.40 |
3.31 |
| 4.06 |
3.40 |
| 4.76 |
3.40 |
| 5.25 |
3.50 |
| 8.44 |
3.22 |
| |
|
| Plainfield loamy soil |
|
| 2.64 |
4.14 |
| 2.92 |
4.28 |
| 3.48 |
4.35 |
| 4.81 |
4.12 |
| 7.58 |
4.30 |
| 8.13 |
4.35 |
Source: University of Wisconsin
Working with corn and soybeans, McLean and coworkers at Ohio State changed
the Ca:Mg ratio in soils at 13 sites. The results of that study are listed
in Table 2.
Looking at the five sites that produced the highest yield, the Ca:Mg ratio
varied from 5.7 to 26.8 and 5.7 to 14.3 in 1975 and 1976 respectively. For
the five sites that produced the lowest yield, the ratio varied from 5.8 to
21.5 and 5.0 to 16.0 in 1975 and 1976 respectively.
Based on the results of this study, it was obvious that the ratio had no effect
on corn production. A similar consideration of ratios and soybean yields
leads to a similar conclusion.
Table 2. Calcium/magnesium ratios at five sites that produced
the highest corn yields and five sites that produced the lowest corn yield.
| Yield Level |
Calcium/Magnesium
Ratio |
| |
1975 |
1976 |
| five highest yielding locations |
5.7 to 26.8 |
5.7 to 26.8 |
| five lowest yielding location |
5.8 to 21.5 |
5.0 to 16.0 |
More recently, a study was conducted near Rochester to evaluate the effect
of calcium/magnesium ratios on alfalfa and soybean production. The
relevant properties of the soil at the experimental site are listed in Table
3. Both the pH and soil test values for potassium were low. Therefore,
a response to potash fertilizer and lime would be expected.
Table 3. Relevant soil properties at the experimental site at
Rochester.
| soil pH |
5.6 |
| Bray P |
29 ppm |
| Soil Test K |
57 ppm |
| Exchangeable calcium |
5.3 milliequivalents/100 grams |
| Exchangeable magnesium |
1.3 milliequivalents/100 grams |
| Calcium/magnesium ratio |
4.1 |
The treatments that were applied and the corresponding yields of soybean and
alfalfa are listed in Table 4. This initial calcium/magnesium ratio was
not 6.5 to 1. It was lower.
In looking at yields in Table 4, yield of both crops was increased by the application
of lime. With an initial soil pH of 5.6, this would be expected. All
treatments were fertilized with adequate rates of phosphate, potash, sulfur
and boron. Neither the type of lime (calcitic, dolomtic) nor the
use of additional magnesium affected the yield of both crops.
Table 4. Soybean and alfalfa yield as affected by application
of calcitic and dolomitic limestone as well as additional magnesium.
| Lime Source |
magnesium added |
lime rate |
total magnesium applied |
soybean |
alfalfa |
| |
lb./acre |
lb. EMP/acre |
1b./acre |
bu/acre |
ton/acre |
| none |
--- |
--- |
--- |
42.4 |
1.82 |
| calcitic |
0 |
3500 |
0 |
46.0 |
2.24 |
| calcitic |
300 |
3500 |
300 |
46.3 |
2.08 |
| dolomitic |
0 |
3500 |
385 |
49.3 |
2.30 |
| dolomitic |
300 |
3500 |
685 |
46.3 |
2.31 |
Crop yield did not decrease as the total amount of applied magnesium increased. This
is clear evidence that magnesium soils does not have a negative effect on crop
growth and production. In addition, the calcium/magnesium ratio was probably
altered as the total amount of applied magnesium increased. Since there
was no change in yield, there was no indication that the calcium/magnesium
ratio had any effect on crop production.
The effect of calcium/magnesium ratio on crop production was evaluated by
Dr. Black of Iowa State University. His conclusion was: "The values
suggested by Bear, Prince, and Malcolm (1945), Graham (1959), and Baker and
Amacher (1981) all represent a good educated guess regarding satisfactory
exchangeable cation ratios in most soils for most crops. The fact is, though,
that research has not demonstrated that there is an optimum exchangeable
cation ratio for any crop."
This statement is an accurate summary of the research that has evaluated the
effect of calcium/magnesium ratios on crop production. There is no need
to believe that the ratio should be used in making fertilizer recommendations. It's
an outdated, antique concept that has no value in high yield, modern agriculture.
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